what is free chlorine and combined chlorine
Breakpoint chlorination is the application of sufficient chlorine to maintain a free available chlorine residual. Here is the part where total chlorine comes into play.
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You know that free chlorine combined chlorine total chlorine.
. However the lower antimicrobial effectiveness of chloramines compared to free chlorine requires higher combined residuals andor longer contact times which are often available in distribution systems. You subtract the amount of free chlorine from the total chlorine to get your combined chlorine level. This figure is what is known as chlorine demand.
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